Waters TOC/VOC EPA vials manufacturer--glass sample vials. The 40 ml vials should contain 10 ml of organic-free water for an un-preserved sample or approximately 10 ml of organic-free water and a preservative. It is recommended that the 40 ml vials be prepared and weighed by the laboratory (commercial sources are available which supply preserved and tared vials). EPA, TOC and Scintillation Vials and Caps - Crawford Scientific