2017/7/12 · COD was determined by a colorimetric method (Hach ® Digestion Method 8000) using a Hach DR/2000 spectrophotometer (620 nm) and Hach ® High Range Plus (0 to 15,000 mg L-1) COD vials. The vials were digested in a multi-tube block heater (120 C, 2 h).